Material scientists at ETH Zurich and the Max Planck Institute of
Colloids and Interfaces in Potsdam have developed a new type of sensor
that can measure carbon dioxide (CO2). Compared with existing sensors,
it is much smaller, has a simpler construction, requires considerably
less energy and has an entirely different functional principle. The new
sensor consists of a recently developed composite material that
interacts with CO2 molecules and changes its conductivity depending on
the concentration of CO2 in the environment. ETH scientists have created
a sensor chip with this material that enables them to determine CO2
concentration with a simple measurement of electrical resistance.
The basis of the composite material is a chain-like macromolecule
(polymer) made up of salts called ionic liquids, which are liquid and
conductive at room temperature. The name of the polymers is slightly
misleading as they are called «poly(ionic liquid)s» (PIL), although they
are solid rather than liquid.
Unexpected properties
Scientists worldwide are currently investigating these PIL for use in
different applications, such as batteries and CO2 storage. From their
work it is known that PIL can adsorb CO2. “We asked ourselves if we
could exploit this property to obtain information on the concentration
of CO2 in the air and thereby develop a new type of gas sensor,” says
Christoph Willa, doctoral student at the Laboratory for Multifunctional
Materials.
Willa and Dorota Koziej, a team leader in the laboratory, eventually
succeeded by mixing the polymers with specific inorganic nanoparticles
that also interact with CO2. By experimenting with these materials, the
scientists were able to produce the composite. “Separately, neither the
polymer nor the nanoparticles conduct electricity,” says Willa. “But
when we combined them in a certain ratio, their conductivity increased
rapidly.”
Chemical changes in the material
It was not only this that astonished the scientists. They were also
surprised that the conductivity of the composite material at room
temperature is CO2-dependent. “Until now, chemoresistive materials have
displayed these properties only at a temperature of several hundred
degrees Celsius,” explains Koziej. Thus, existing
CO2 sensors made from
chemoresistive materials had to be heated to a high operating
temperature. With the new composite material, this is not necessary,
which facilitates its application significantly.
Exactly how the CO2-dependant changes in conductivity were produced is
not yet clear; however, the scientists have found indications that a
chemical change induced by the presence of CO2 occurs foremost at the
interface between the nanoparticles and the polymers at the nanometre
scale. “We think that CO2 effects the mobility of the charged particles
in the material,” says Koziej.
Breathing gauges for scuba divers
With the new sensor, scientists are able to measure CO2 concentration
over a wide range – from a concentration of 0.04 volume percent in the
earth’s atmosphere to 0.25 volume percent.
Existing devices that can detect CO2 measure the optical signal and
capitalise on the fact that CO2 absorbs infrared light. In comparison,
researchers believe that with the new material much smaller, portable
devices can be developed that will require less energy. According to
Koziej, “portable devices to measure breathing air for scuba diving,
extreme altitude mountaineering or medical applications are now
conceivable”.
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