This paper details the design and fabrication of an
integrated optical oxygen sensor using a select oxygen-sensitive
fluorescent dye, tris(2,2′-bipyridyl) dichlororuthenium(II) hexahydrate,
combined with polymeric waveguides that are fabricated on a glass substrate.
The sensor uses evanescent interaction of light confined
within the waveguide with the dye that is immobilized on an SU-8 waveguide
surface. Adhesion of the dye to the integrated waveguide surface is
accomplished using a unique process of spin-coating/electrostatic
layer-by-layer formation.
The SU-8 waveguide was chemically modified to allow the
deposition process. Exposure of the dye molecules to the analyte and subsequent
chemical interaction is achieved by directly coupling the fluid channel to the
integrated waveguide. The completed sensor was linear in the dissolved oxygen
across a wide range of interest and had a sensitivity of 0.6 ppm.
A unique fabrication aspect of this sensor is the inherent
simplicity of the design, and the resulting rapidity of fabrication, while
maintaining a high degree of functionality and flexibility.
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